Hydrogen Sulfide
This is the organizing page for research related to hydrogen sulfide in Public Lab.
What is hydrogen sulfide, what are its effects, and where is it found?
Hydrogen sulfide, with the chemical formula H2S, is a flammable gas that has a pungent odor at low concentrations and is odorless at higher concentrations. It can be a respiratory irritant and a neurotoxin. For more information about hydrogen sulfide health effects, please see: https://publiclab.org/wiki/hydrogen-sulfide-effects.
Hydrogen sulfide is naturally formed in low-oxygen conditions with sulfate present, such as in organic-rich sediments and thus in petrochemical source rocks. Upon exposure to oxygen, hydrogen sulfide readily oxidizes to sulfur dioxide or sulfate, and generally reacts within hours to days. For information about hydrogen sulfide sources and spatial and temporal variation, please see: https://publiclab.org/wiki/hydrogen-sulfide-environment
How are hydrogen sulfide emissions and exposures regulated?
In the United States, hydrogen sulfide emissions are only federally regulated to the extent that they contribute to sulfur dioxide formation, and thus acid rain. These emissions are regulated through the Prevention of Significant Deterioration of major stationary sources review and permitting. Exposure to hydrogen sulfide is mostly regulated in terms of occupational exposure, with very few states regulating ambient exposure to this toxin. For detailed information of environmental and occupational hydrogen sulfide regulations, please see: https://publiclab.org/wiki/hydrogen-sulfide-regulations
How can hydrogen sulfide be measured?
While there is no federal regulatory method for hydrogen sulfide in the US, labs, agencies, and oilfield workers often measure hydrogen sulfide gas through these means, whose cost and sensitivity vary pretty widely:
- badges or glass tubes that change color
- continuously sampling electronic sensors, some worn by oilfield workers
- air grab sampling, as by the Bucket Brigades, tested with gas chromatography
We're compiling information about the pros, cons, prices, and sensitivity/limitations about these techniques. See the Questions section below to help build out this list. (we'll link in a question here once it's been posted: "What are different commercially available hydrogen sulfide detection methods?")
For more information about different measurement methods, see: Hydrogen Sulfide Detection
Do-It-Yourself approaches to detection
There are three prototype, low-cost hydrogen sulfide detection methods currently being explored by Public Lab community members. These include:
- a method using photographic paper
- a copper rod method
- a technique using a Do-It-Yourself potentiostat
- commercial electronic H2S sensors connected to a computer or #arduino
Help out! Please help link the above bullet points to corresponding pages across this site.
Questions
We can't make progress on these techniques and resources without addressing our unknowns. Please ask questions to help shape the direction of our work!
Related pages
See other related wiki pages here
Activities
These activities are to guide you to test out hydrogen sulfide detection methods or use these tools in the field:
| Purpose | Category | Status | Author | Time | Difficulty | Replications |
|---|---|---|---|---|---|---|
| Qualitative Time Lapse of Copper Corrosion | - | - | @ErikHanley11 | - | - | 0 replications: Try it » |
| Copper Strip Test Preparation Using Solvents | - | - | @ErikHanley11 | - | - | 0 replications: Try it » |
| Copper Sheet Hydrogen Sulfide Detection Activity | test-limits | draft | @gretchengehrke | 1h | easy | 2 replications: Try it » |
| Hydrogen Sulfide Testing With Black and White Film | - | - | @jschaffr | - | - | 3 replications: Try it » |
| Two Rounds of Copper Rod Test Making | - | - | @ErikHanley11 | - | - | 0 replications: Try it » |
Activities should include a materials list, costs and a step-by-step guide to construction with photos. Learn what makes a good activity here.
Where can I find more information?
Two particularly good resources are listed below. Other hydrogen sulfide wiki pages (mentioned above) include additional relevant resources.
Agency for Toxic Substance and Disease Registry. 2016. Hydrogen Sulfide Fact Sheet. https://www.atsdr.cdc.gov/ToxProfiles/tp114-c1-b.pdf.
National Research Council. 2010. Acute Exposure Guidelines. https://www.epa.gov/sites/production/files/2014-11/documents/hydrogen_sulfide_final_volume9_2010.pdf.